Plasmonic O2 Dissociation and Spillover Expedite Selective Oxidation of Primary C–H Bonds
Open access
Date
2021-12-14Type
- Journal Article
Abstract
Manipulating O2 activation via nanosynthetic chemistry is critical in many oxidation reactions central to environmental remediation and chemical synthesis. Based on a carefully-designed plasmonic Ru/TiO2–x catalyst, we first report a room-temperature O2 dissociation and spillover mechanism that expedites the "dream reaction" of selective primary C–H bond activation. Under visible light, surface plasmons excited in the negatively-charged Ru nanoparticles decay into hot electrons, triggering spontaneous O2 dissociation to reactive atomic •O. Acceptor-like oxygen vacancies confined at the Ru-TiO2 interface free Ru from oxygen-poisoning by kinetically boosting the spillover of •O from Ru to TiO2. Evidenced by an exclusive isotopic O-transfer from 18O2 to oxygenated products, •O displays a synergistic action with native •O2– on TiO2 that oxidizes toluene and related alkyl aromatics to aromatic acids with extremely high selectivity. We believe the intelligent catalyst design for desirable O2 activation will contribute viable routes for synthesizing industrially important organic compounds. Show more
Permanent link
https://doi.org/10.3929/ethz-b-000514602Publication status
publishedExternal links
Journal / series
Chemical ScienceVolume
Pages / Article No.
Publisher
Royal Society of ChemistrySubject
O2 dissociation; Photocatalysis; C-H bond activation; Oxygen spillover; SelectivityOrganisational unit
03887 - Wang, Jing / Wang, Jing
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