Formation of Die Soldering and the Influence of Alloying Elements on the Intermetallic Interface
Open access
Date
2021-04-01Type
- Journal Article
Abstract
Die soldering of die castings is a serious problem in the aluminum casting industry. The precise mechanism, the influence of the alloy composition, and the options for prevention have not yet been fully elaborated. A well-established solution for alloys with low iron content is the addition of manganese. However, up to 0.8 wt.% is necessary, which increases the amount of brittle phases in the material and consequently reduces ductility. Immersion tests with 1.2343 tool steel and pure aluminum as well as a hypoeutectic AlSi-alloy with Mn, Mo, Co, and Cr additions were carried out to systematically investigate the formation of die soldering. Three different intermetallic layers and a scattered granular intermetallic phase formed at the interface between steel and Al-alloy after immersion into the melt for a duration of 6 min at 710 °C. The combined presence of the irregular, needle-shaped β-Al5FeSi phase and the surrounding alloy was responsible for the bond between the two components. Mn and Mo inhibited the formation of the β-phase, and instead promoted the αC-Al15(Fe,X)3Si2 phase. This led to an evenly running boundary to the AlSi-alloy and thus prevented bonding. Cr has proven to be the most efficient addition against die soldering, with 0.2 wt.% being sufficient. Contrary to the other elements investigated, Cr also reduced the thickness of the intermetallic interface. Show more
Permanent link
https://doi.org/10.3929/ethz-b-000478128Publication status
publishedExternal links
Journal / series
MaterialsVolume
Pages / Article No.
Publisher
MDPISubject
aluminum; die soldering; intermetallic phases; high-pressure die casting; chromium; manganese; molybdenum; cobaltOrganisational unit
03661 - Löffler, Jörg F. / Löffler, Jörg F.
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