Selective Hydrogenation of CO2 to CH3OH on Supported Cu Nanoparticles Promoted by Isolated TiIV Surface Sites on SiO2
dc.contributor.author
Noh, Gina
dc.contributor.author
Lam, Erwin
dc.contributor.author
Alfke, Jan L.
dc.contributor.author
Larmier, Kim
dc.contributor.author
Searles, Keith
dc.contributor.author
Wolf, Patrick
dc.contributor.author
Copéret, Christophe
dc.date.accessioned
2020-01-14T13:30:05Z
dc.date.available
2019-11-07T08:33:46Z
dc.date.available
2019-11-07T08:37:38Z
dc.date.available
2020-01-14T13:30:05Z
dc.date.issued
2019-03-07
dc.identifier.issn
1864-564X
dc.identifier.issn
1864-5631
dc.identifier.other
10.1002/cssc.201900134
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/375747
dc.identifier.uri
http://hdl.handle.net/20.500.11850/375899
dc.identifier.doi
10.3929/ethz-b-000375899
dc.description.abstract
Small and narrowly distributed Cu nanoparticles, supported on SiO2 decorated with isolated TiIV sites, prepared via surface organometallic chemistry, show significantly improved CO2 hydrogenation activity and CH3OH selectivity compared to the corresponding Cu nanoparticles supported on SiO2. We propose that these isolated Lewis acid TiIV sites, evidenced by UV-Vis spectroscopy, stabilize surface intermediates at the interface between Cu nanoparticles and the support.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Wiley
en_US
dc.rights.uri
http://rightsstatements.org/page/InC-NC/1.0/
dc.subject
titanium
en_US
dc.subject
ch3oh synthesis
en_US
dc.subject
Surface organometallic chemistry (SOMC)
en_US
dc.subject
heterogeneous catalysis
en_US
dc.subject
CO2 hydrogenation
en_US
dc.title
Selective Hydrogenation of CO2 to CH3OH on Supported Cu Nanoparticles Promoted by Isolated TiIV Surface Sites on SiO2
en_US
dc.type
Journal Article
dc.rights.license
In Copyright - Non-Commercial Use Permitted
dc.date.published
2019-01-14
ethz.journal.title
ChemSusChem
ethz.journal.volume
12
en_US
ethz.journal.issue
5
en_US
ethz.journal.abbreviated
ChemSusChem
ethz.pages.start
968
en_US
ethz.pages.end
972
en_US
ethz.size
14 p. accepted version
en_US
ethz.version.deposit
acceptedVersion
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Weinheim
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03872 - Copéret, Christophe / Copéret, Christophe
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03872 - Copéret, Christophe / Copéret, Christophe
ethz.date.deposited
2019-03-17T03:29:41Z
ethz.source
SCOPUS
ethz.source
FORM
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.date.embargoend
2020-01-14
ethz.rosetta.installDate
2019-11-07T08:37:50Z
ethz.rosetta.lastUpdated
2021-02-15T07:17:56Z
ethz.rosetta.versionExported
true
dc.identifier.olduri
http://hdl.handle.net/20.500.11850/331776
dc.identifier.olduri
http://hdl.handle.net/20.500.11850/375747
ethz.COinS
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