In Situ Observation of Topotactic Linker Reorganization in the Aperiodic Metal-Organic Framework TRUMOF-1
dc.contributor.author
Greenbaum, Guy
dc.contributor.author
Doheny, Patrick W.
dc.contributor.author
Paraoan, Robert A. I.
dc.contributor.author
Kholina, Yevheniia
dc.contributor.author
Michalik, Stefan
dc.contributor.author
Cassidy, Simon J.
dc.contributor.author
Yeung, Hamish H. -M.
dc.contributor.author
Goodwin, Andrew L.
dc.date.accessioned
2024-10-09T12:24:01Z
dc.date.available
2024-10-09T04:55:52Z
dc.date.available
2024-10-09T12:24:01Z
dc.date.issued
2024-10-09
dc.identifier.issn
0002-7863
dc.identifier.issn
1520-5126
dc.identifier.other
10.1021/jacs.4c09487
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/698673
dc.identifier.doi
10.3929/ethz-b-000698673
dc.description.abstract
We use in situ synchrotron X-ray diffraction measurements to monitor the solvothermal crystallization mechanism of the aperiodic metal-organic framework TRUMOF-1. Following an initial incubation period, TRUMOF-1 forms as a metastable intermediate that subsequently transforms into an ordered product with triclinic crystal symmetry. We determine the structure of this ordered phase, which we call msw-TRUMOF-1, and show that it is related to TRUMOF-1 through topotactic reorganization of linker occupancies. Our results imply that the connectivity of TRUMOF-1 can be reorganized, as required for data storage and manipulation applications.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
American Chemical Society
en_US
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
dc.title
In Situ Observation of Topotactic Linker Reorganization in the Aperiodic Metal-Organic Framework TRUMOF-1
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution 4.0 International
dc.date.published
2024-09-26
ethz.journal.title
Journal of the American Chemical Society
ethz.journal.volume
146
en_US
ethz.journal.issue
40
en_US
ethz.journal.abbreviated
J. Am. Chem. Soc.
ethz.pages.start
27262
en_US
ethz.pages.end
27266
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.status
published
en_US
ethz.date.deposited
2024-10-09T04:55:56Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2024-10-09T12:24:02Z
ethz.rosetta.lastUpdated
2024-10-09T12:24:02Z
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Journal Article [131648]