Dopant incorporation into garnet solid solutions—a breakdown of Goldschmidt’s first rule
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Datum
2003Typ
- Journal Article
ETH Bibliographie
yes
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Abstract
Atomistic simulations suggest trace elements are more soluble in a 50∶50 pyrope (Mg3Al2Si3O12)–grossular (Ca3Al2Si3O12) garnet mixture than in either end-member; consistent with partitioning experiments, and, contrary to Goldschmidt’s first rule, large trace element cations may substitute for Mg2+, small trace elements for Ca2+. Mehr anzeigen
Publikationsstatus
publishedExterne Links
Zeitschrift / Serie
Chemical CommunicationsBand
Seiten / Artikelnummer
Verlag
Royal Society of ChemistryETH Bibliographie
yes
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