Coil-to-Rod Transition of Conjugated Polymers Prepared by Cyclopolymerization of 1,6-Heptadiynes

Abstract

We report the conformational change resulting from the coil-to-rod transition in conjugated polymers prepared by the cyclopolymerization of 1,6-heptadiyne derivatives (poly(cyclopentenylene-vinylene), PCPV). By aging a PCPV solution under various conditions, we observed dramatic changes in their absorption spectra (appearance of a 00 vibronic peak) and an increase in the MarkHouwinkSakurada shape parameter, thereby confirming the coil-to-rod transition of the polymer. Further studies using NMR spectroscopy and various control experiments demonstrated that the coil-to-rod transformation resulted from the cis-to-trans isomerization of the conjugated olefins by a radical mechanism.