Mineralization of wood by calcium carbonate insertion for improved flame retardancy
Open access
Datum
2016-09Typ
- Journal Article
Abstract
Wood can be considered as a highly porous, three-dimensional organic scaffold. It can be mineralized to create hierarchically structured organic-inorganic hybrid materials with novel properties. In the present paper, the precipitation of CaCO3 mineral in Norway spruce and European beech wood has been studied by alternating impregnation with aqueous and alcoholic electrolyte solutions. Microstructural imaging by SEM and confocal Raman microscopy shows the distribution of calcite and vaterite as two CaCO3 polymorphs, which are deposited deep inside the cellular structure of the wood. The confined microenvironment of the wood cell wall seems to favor a formation of vaterite, as visible by XRD and Raman spectroscopy. In view of a practical application, the mineralization of wood opens up ways for sustainable wood-based hybrid materials with a significantly improved fire resistance, as proven via pyrolysis combustion flow calorimetry and cone calorimetry tests. Beyond that, this versatile solute-exchange approach provides an opportunity for the incorporation of a broad range of different mineral phases into wood for novel material property combinations. Mehr anzeigen
Persistenter Link
https://doi.org/10.3929/ethz-b-000119900Publikationsstatus
publishedExterne Links
Zeitschrift / Serie
HolzforschungBand
Seiten / Artikelnummer
Verlag
De GruyterThema
Calcite; Calcium carbonate; Cone calorimetry; Fire retardant; Hybrid material; Mineral; Mineralized woodOrganisationseinheit
03917 - Burgert, Ingo / Burgert, Ingo
Anmerkungen
It was possible to publish this article open access thanks to a Swiss National Licence with the publisher.